(±)-(4aR,5R,8S,8aR)-8-(tert-Butyl­dimethyl­sil­yloxy)-2,5,8a-trimethyl-4a,5,8,8a-tetra­hydro­naphthalene-1,4-dione

نویسندگان

  • Felix N. Delling
  • Julio Zukerman-Schpector
  • Timothy J. Brocksom
  • Ursula Brocksom
  • Fernanda G. Finelli
  • Edward R. T. Tiekink
چکیده

In the title compound, C19H30O3Si, both rings adopt a half-boat conformation. Overall, the mol-ecule approximates a U-shape as the cyclo-2-ene-1,4-dione and butyl-dimethyl-sil-yloxy substituents lie to the same side of the central cyclo-hexene ring; the methyl substituent lies to the other side of the mol-ecule. In the crystal, linear supra-molecular chains along the b axis are sustained by C-H⋯O inter-actions.

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عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013