Carbon Nanotubes as Supports for Palladium and Bimetallic Catalysts for Use in Hydrogenation Reactions
نویسنده
چکیده
School of Chemistry, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa Email: ‡[email protected]; *[email protected] Carbon nanotubes (CNTs) possess unique properties which make them competitive with conventional catalyst supports. This short review collates fi ndings from many research groups on the benefi ts of palladium/carbon nanotubes in hydrogenation reactions. The effects of modifi ed CNTs and bimetallic platinum group metal (pgm) catalyst/CNT systems for hydrogenation reactions are also discussed.
منابع مشابه
Nanosized Pd-Au bimetallic phases on carbon nanotubes for selective phenylacetylene hydrogenation.
Palladium (Pd)-catalyzed selective hydrogenation of alkynes has been one of the most studied hydrogenation reactions in the last century. However, kinetic studies conducted to reveal the catalyst's active centers have been hindered because of dynamic surface changes on Pd during the reaction. In the present study, bimetallic Pd-Au nanoparticles supported on carbon nanotubes have been synthesize...
متن کاملSeparation and Recovery of Platinum and Palladium from Spent Petrochemical Catalysts Using Activated Carbon, Analysis of Two Kind of Most Used Catalysts in Petro Chemistry
The goal of this work is the separation and recovery of platinum and palladium from spent catalyst. The recovery consisted of separating the maximum amount of platinum and palladium from catalysts and changing them into usable forms. The petroleum and petrochemical units use Pt and Pd catalyst for reactions such as reforming and hydrogenation. Because these materials contain valuable metals...
متن کاملNanostructured carbon-metal oxide hybrids as amphiphilic emulsion catalysts.
Nanohybrids composed of "onion-like" carbon, single-walled (SWCNTs) or multi-walled carbon nanotubes (MWCNTs) fused to silica or alumina particles have been compared as stabilizers of water/oil emulsions and interfacial catalysts. The amphiphilic character of these nanohybrids makes them effective in stabilizing emulsions (up to 85 % of total volume) comprising of small droplets (less than 40 μ...
متن کاملSupport Screening Studies on the Hydrogenation of Levulinic Acid to -Valerolactone in Water Using Ru Catalysts
γ-Valerolactone (GVL) has been identified as a sustainable platform chemical for the production of carbon-based chemicals. Here we report a screening study on the hydrogenation of levulinic acid (LA) to GVL in water using a wide range of ruthenium supported catalysts in a batch set-up (1 wt. % Ru, 90 ◦C, 45 bar of H2, 2 wt. % catalyst on LA). Eight monometallic catalysts were tested on carbon b...
متن کاملAb initio (first principle) material modeling study on Lio adsorbed by palladium-cobalt (PdCo) nanoparticles
PdCo subnanoalloys have been commonly used as a catalytic material in some important chemicalreactions, involving in fisher-tropsch reactions, and oxygen reduction reactions. In terms ofunderstanding the role of catalysis, these smallest bimetallic nanoparticles provide the simplestprototypes of Pd-Co bimetallic catalysts for different compositions. In this study, the effect o...
متن کامل