Study of decomposition products by gas chromatography-mass spectrometry and ion chromatography-electrospray ionization-mass spectrometry in thermally decomposed lithium hexafluorophosphate-based lithium ion battery electrolytes

نویسندگان

  • Vadim Kraft
  • Waldemar Weber
  • Martin Grützke
  • Sascha Nowak
چکیده

In this work, the thermal decomposition of a lithium ion battery electrolyte (1 M LiPF6 in ethylene carbonate/ ethyl methyl carbonate, 50/50 wt%) with a focus on the formation of organophosphates was systematically studied. The quantification of non-ionic dimethyl fluorophosphate and diethyl fluorophosphate was performed with synthesized standards by gas chromatography-mass spectrometry. Due to absence of commercially available or synthesized standards for the monitoring of ionic methyl fluorophosphate, ethyl fluorophosphate and ethylene phosphate a method working with ion chromatography-electrospray ionization-mass spectrometry was developed, where dibutyl phosphate was used as an internal standard. In addition, an ion chromatography conductivity detection method with short analysis time for simultaneous determination and quantification of F , PF6 and BF4 was developed. The formation and degradation of analytes was studied to show the dependence of different temperatures, electrolyte volumes and separator materials. The thermal aging experiments were carried out in gas-tight aluminum vials at 80 C for three weeks. After the storage time, the samples were diluted with the appropriate analysis solvents and investigated with gas chromatography-mass spectrometry, ion chromatography and ion chromatography-electrospray ionization-mass spectrometry. Finally, the thermal degradation of the electrolyte at 85 C after five days in aluminum and glass vials was studied.

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تاریخ انتشار 2015