Delignification of Sugarcane Bagasse with Alkali and Peracetic Acid and Characterization of the Pulp
نویسندگان
چکیده
Sugarcane bagasse was delignified with alkali and peracetic acid in a two-stage process to obtain pulps with high yield and low kappa number. The experimental results indicated that alkali pretreatment prior to peracetic acid (PAA) delignification could significantly reduce PAA loading by partially removing lignin and swelling the fibers. An optimum condition for the two-stage delignification was obtained for pulping of sugarcane bagasse. The pulps were further characterized by chemical composition analysis, strength property tests, Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), and Thermal Gravimetric Analysis (TGA). It was found that the alkali-PAA process could be conducted under milder conditions with resulting higher pulping selectivity, higher degree of polymerization (DP), and superior mechanical properties of pulps, compared to the kraft pulping process. Both kraft pulps and alkali-PAA pulp had similar FTIR spectra, XRD spectra, and TGA (DTG) curves. However, further analysis indicated that the alkali-PAA pulp had higher infrared crystallization index and cellulose crystallinity.
منابع مشابه
Isolation and characterization of acetylated glucuronoarabinoxylan from sugarcane bagasse and straw.
Sugarcane bagasse and straw are generated in large volumes as by-products of agro-industrial production. They are an emerging valuable resource for the generation of hemicellulose-based materials and products, since they contain significant quantities of xylans (often twice as much as in hardwoods). Heteroxylans (yields of ca 20% based on xylose content in sugarcane bagasse and straw) were succ...
متن کاملComparative study on chemical pretreatment (acid and ozone) methods for improving enzymatic digestibility of sugar cane bagasse
Sugarcane bagasse contains cellulose, lignin and hemicellulose, 39-42%, 20-25% and 25-27% respectively. So it is can be used as a sugar source in many processes. Lignin and hemicellulose must be removed before hydrolysis of cellulose. Several different pretreatment approaches have been studied. The purpose of this research is comparison of acid, ozone and combination of ozone-acid as pretreatme...
متن کاملBiodegradation and delignification of sugar cane bagasse of pulp and paper mill effluent by Cryptococcus albidus for production of bioethanol
The study aims to extend the range of resources from which ethanol may be made from sugar cane bagasse which is used primarily for preparation of pulp and paper. Seven fungal strains isolated from sediment and degraded wood of pulp and paper mill effluent in which one strain identified by 18S rDNA internal transcribed spacer (ITS) as Cryptococcus albidus had higher decolourization and delignifi...
متن کاملStudy of the Luffa Cylindrica, Part II: Pulp Elaboration and Paper Characterization
This study was devoted to the development of pulp Luffa Cclindrica and its characterization paper (annual plant fiber of the family Cucurbitaceae). Baking at soda helps to achieve a high level of delignification (Kappa ≤ 10) and high yield (≈ 67%).The beatability stack Valley is comparable to refined wood fibers, the fibers develop a normally time with good hydrophilic pro...
متن کاملComparative study on chemical pretreatment (acid and ozone) methods for improving enzymatic digestibility of sugar cane bagasse
Sugarcane bagasse contains cellulose, lignin and hemicellulose, 39-42%, 20-25% and 25-27% respectively. So it is can be used as a sugar source in many processes. Lignin and hemicellulose must be removed before hydrolysis of cellulose. Several different pretreatment approaches have been studied. The purpose of this research is comparison of acid, ozone and combination of ozone-acid as pretreatme...
متن کامل