A novel tricyanoruthenium(III) building block for the construction of bimetallic coordination polymers.
نویسندگان
چکیده
Reaction of excess cyanide with a ruthenium(VI) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(III) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-Ru(III) magnetic materials.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 33 شماره
صفحات -
تاریخ انتشار 2010