2,2′-(Decane-1,10-diyl)dibenzimidazolium dichloride trihydrate
نویسندگان
چکیده
The organic cation in the title compound, C(24)H(32)N(4) (2+)·2Cl(-)·3H(2)O, is situated on an inversion centre. The cations, anions and water mol-ecules are linked via N-H⋯O, N-H⋯Cl, O-H⋯O and O-H⋯Cl hydrogen bonds and C-H⋯π interactions, forming a three-dimensional framework.
منابع مشابه
Redetermination of chlorido(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)gold(I) dichloride trihydrate at 173 K. Corrigendum
The title of the paper by Friedrich, Maguire, Martincigh, McKay & Pietersen [Acta Cryst. (2008), E64, m1240] is corrected.[This corrects the article DOI: 10.1107/S1600536808027943.].
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The redetermined structure of the title compound, [AuCl(C(15)H(11)N(3))]Cl(2)·3H(2)O, at 173 (2) K is reported. The structure displays O-H⋯Cl and O-H⋯O hydrogen bonding. The distance of one of the chloride ions from the gold(I) atom [5.047 (1) Å] differs from that determined previously.
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The title compound, C(24)H(46)N(4)O(8) (2+)·2Cl(-)·2H(2)O, was synthes-ized by the hydrolysis of tetra-ethyl 2,2',2'',2'''-(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane-1,4,8,11-tetra-yl) tetra-acetate in hydro-chloric acid solution. The crystal structure of the title compound consists of a 14-membered C(10)N(4) centrosymmetric cationic macrocycle which inter-acts with the ch...
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