(4-Chlorobenzohydrazidato-κ2 N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ2 N 1,O)-3-phenylpropionato(2−)-κO 1]oxidovanadium(V) methanol monosolvate
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چکیده
The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds about a center of inversion, generating a dimer.
منابع مشابه
(4-Chlorobenzohydrazidato-κ2 N′,O)[2-(4-chlorobenzoylhydrazono-κ2 N,O)propionato(2−)-κO]oxidovanadium(V)
In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro-benzoyl-hydrazidate anion and O,N,O'-chelated by the (chloro-benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds i...
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