(4-Chloro­benzohydrazidato-κ2 N′,O)[2-(4-chloro­benzoyl­hydrazinyl­idene-κ2 N 1,O)-3-phenyl­propionato(2−)-κO 1]oxidovanadium(V) methanol monosolvate

نویسندگان

  • Hon Wee Wong
  • Kong Mun Lo
  • Seik Weng Ng
چکیده

The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds about a center of inversion, generating a dimer.

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(4-Chloro­benzohydrazidato-κ2 N′,O)[2-(4-chloro­benzoyl­hydrazono-κ2 N,O)propionato(2−)-κO]oxidovanadium(V)

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010