Dinuclear planar chiral ferrocenyl gold(I) & gold(II) complexes.

نویسندگان

  • Marta Ayerbe Garcia
  • Wolfgang Frey
  • Mark R Ringenberg
  • Max Schwilk
  • René Peters
چکیده

Oxidation of Au(I) in the presence of Fe(II) allowed for the synthesis of unique dinuclear ferrocenyl Au(II) complexes via the first reported enantiopure planar chiral ferrocenyl Au(I) complex. (Spectro)electrochemical studies show that oxidation at Fe(II) is favoured, but DFT studies suggest that the energy differences for oxidation of one or the other metal should be quite small.

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عنوان ژورنال:
  • Chemical communications

دوره 51 94  شماره 

صفحات  -

تاریخ انتشار 2015