(Benzene-1,3-dicarboxyl­ato-κ2 O 1,O 1′)(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ4 N 1,N 12,N 15,N 26)cadmium(II) benzene-1,3-dicarboxylic acid solvate

نویسندگان

  • Zhi-Fang Jia
  • Jian-Fang Ma
  • Lai-Ping Zhang
چکیده

In the title compound, [Cd(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))]·C(8)H(6)O(4), the Cd(II) atom is six-coordinated by four N atoms from the macrocyclic ligand and two O atoms from a benzene-1,3-dicarboxyl-ate ligand. The complex mol-ecules are linked by N-H⋯O hydrogen bonds, forming a one-dimensional chain structure along the b axis. The chains are further connected through N-H⋯O and O-H⋯O hydrogen bonds between the complex mol-ecule and an uncoordinated benzene-1,3-dicarboxylic acid mol-ecule, resulting in a two-dimensional supra-molecular network.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008