Unique nanoscale {Cu(II)36Ln(III)24} (Ln = Dy and Gd) metallo-rings.
نویسندگان
چکیده
Two unprecedented 3d-4f hexagonal metallo-rings {Ln(24)Cu(36)} (Ln = Dy and Gd) with a diagonal dimension of about 4.6 nm were facilely synthesized by self-assembly of Cu(II), Ln(III) nitrates and benzoate in the presence of triethylamine. Magnetic studies show slow relaxation behaviour for the dysprosium analogue and a large magnetocaloric effect (MCE) for the gadolinium analogue.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 43 شماره
صفحات -
تاریخ انتشار 2012