Symmetrically and unsymmetrically bridged methylenebis(allopurinols): synthesis of dimeric potential anti-gout drugs.

Synthesis of Binuclear Monohydroxo Bridged Copper(II) Complexes with 1,10-Phenanthroline and 4,4'-Dimethyl-2,2'-Bipyridine

Tow new compound of type [(chelate)2Cu-OH-Cu(chelate)2] X3.nH2O, where chelate=1,10-phenanthroline; X=Cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine;  (n=5) have been synthesized and their properties investigated. The complexes show room temperature magnetic moment order of 1.0 B.M. per copper atom. The X-band ESR spectrum of powdered sample...

New Dinuclear Methoxo-Bridged Manganese(III) complex: Synthesis, Characterization and Usage as New Precursor for Synthesis of Mn2O3 Particles

New dinuclear methoxo-bridged manganese(III) complex [Mn2((MeO-bph)en)2Cl2(m-CH3O)2] (1) was synthesized by template reaction of 2-hydroxy-4-methoxybenzophenone, 1,2-ethanediamine and MnCl2×6H2O with molar ration (1:1:1) in methanol as solvent. The title compound 1 was characterized by...

Ir and Nmr Studies of Symmetrically and Unsymmetrically Bonded N./v-dialkyldithio- Carbamates

Synthesis and characterization of novel grid coordination polymer networks generated from unsymmetrically bridging ligands.

Self-assembly between simple unsymmetrical ligands, such as 1-(3-pyridyl)-2-(4-pyridyl)ethene (L(1)) and 1-methyl-1'-(3-pyridyl)-2-(4-pyrimidyl)ethene (L(2)), and Co(NCS)(2) affords the unprecedented two-dimensional grid coordination polymers [Co(L(1))(2)(NCS)(2)](infinity) (1) and [Co(L(2))(2)(NCS)(2)](infinity) (2), respectively, with novel topological features which cannot be achieved using ...

Synthesis, Characterization and Antibacterial Properties of Some Thiocyanato Bridged Heteronuclear Complexes of Nickel

A series of heterobinuclear, thiocyanato-bridged complexes of cations [M(NH2X)6 ] 2+, and [M(en)3 ] 2+ (where X = H, Ph; M=Cu, Co, Cd, Zn) with anion [Ni(NCS)4 ] 2 –have been prepared by 1:1 molar ratio. The complexes have been characterized by FT-IR, 13C NMR and UV-vis spectroscopy, metal analysis, magnetic and conductance studies. The complexes have the following composition: [M(NH2 X)5 ][Ni(...