Tracking the picosecond deactivation dynamics of a photoexcited iron carbene complex by time-resolved X-ray scattering† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02815f
نویسندگان
چکیده
European Synchrotron Radiation Facility, France. E-mail: [email protected] Department of Chemical Physics, Lund U Sweden Molecular Movies Group, Department of P Lyngby, DK-2800, Denmark Theoretical Chemistry Division, Lund Unive European XFEL GmbH, Holzkoppel 4, 2286 Centre for Analysis and Synthesis, Departm Box 12 4, Lund 22100, Sweden † Electronic supplementary informa 10.1039/c7sc02815f Cite this: Chem. Sci., 2018, 9, 405
منابع مشابه
Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates† †Electronic supplementary information (ESI) available: Experimental procedures, compound characterization data, and X-ray crystallographic data of compounds 4b-Et and 4b-Me. CCDC 1014843 and 1014844. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01027f Click here for additional data file. Click here for additional data file.
متن کامل
Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay† †Electronic supplementary information (ESI) available: Experimental procedures, syntheses, X-ray crystallographic data (CIF), and detailed theoretical discussion of presented and alternative mechanisms. CCDC 1046291. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00398a
متن کامل
A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis† †Electronic supplementary information (ESI) available: Synthetic and spectral details are deposited. CCDC 1035566–1035574. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03675a
متن کامل
Selective photocatalytic hydroxylation and epoxidation reactions by an iron complex using water as the oxygen source† †Electronic supplementary information (ESI) available: Materials, general instrumentation and additional figures. See DOI: 10.1039/c7sc02780j Click here for additional data file.
متن کامل
A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes† †Electronic supplementary information (ESI) available: Optimisation details and full characterisation data. CCDC 940850–940853. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45488f Click here for additional data file.
A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.
متن کامل