A chiral diphosphine as trans-chelate ligand and its relevance to catalysis.
نویسندگان
چکیده
The chiral diphosphine ligand R,R-trans-1,2-C(6)H(10)(NHCOC(6)H(4)PPh(2))(2), 1, gives the fluxional trans-chelate complexes [M(1)]X, 2a-2c, M = Au or Ag. It is suggested that a similar trans-chelate conformation may be present in the catalytic intermediate [Pd(1)].
منابع مشابه
Self-assembled polymers of silver(I) with a chiral diphosphine ligand.
Silver(I) salts, AgX, form self-assembled polymers with the chiral diphosphine ligand R,R-trans-C(6)H(10)(NHCO-2-C(6)H(4)PPh(2))(2), 1, of formula {Ag(2)X(2)(μ-1)}(n) and ring-opening polymerization of the trans chelate complex [Ag(1)]X has given the helical polymer [{Ag(μ-1)}(n)]X(n), when X = CF(3)SO(3).
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 11 شماره
صفحات -
تاریخ انتشار 2010