1-(2-Bromoethyl)-1,4-diazoniabicyclo[2.2.2]octane bromide tetrafluoroborate
نویسنده
چکیده
In the crystal of the title compound, C(8)H(17)BrN(2) (2+)·Br(-)·BF(4) (-), a weak inter-molecular N-H⋯Br hydrogen bond is observed between the cation and the bromide anion. A two-part disorder model was applied to the BF(4) (-) anion with a refined major-minor occupancy ratio of 0.837 (14):0.163 (14).
منابع مشابه
1-(2-Bromoethyl)-1,4-diazoniabicyclo[2.2.2]octane bromide dihydrogen phosphate–phosphoric acid (1/1)
In the crystal structure of the title compound, C(8)H(17)BrN(2) (2+)·Br(-)·H(2)PO(4) (-)·H(3)PO(4), the cations, anions and phospho-ric acid mol-ecules are linked by O-H⋯O, N-H⋯O and O-H⋯Br hydrogen bonds into layers parallel to (101).
متن کامل1-Bromomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridozincate
The reaction of 1-bromo-methyl-1,4-diazo-niabicyclo-[2.2.2]octane bromide, zinc chloride and hydro-chloric acid in water yields the title compound, (C(7)H(15)BrN(2))[ZnCl(4)]. In the crystal, the components are linked by N-H⋯Cl hydrogen bonds. The Zn(II) atom has an approximately tetra-hedral coordination geometry.
متن کامل1,4-Diazoniabicyclo[2.2.2]octane terephthalate
In the title compound, C(6)H(14)N(2+)·C(8)H(4)O(4) (2-), the protonated 1,4-diazo-niabicyclo-[2.2.2]octane cations and the deprotonated terephthalate anions are alternately linked by N-H⋯O hydrogen bonds into chains.
متن کامل1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)
In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra-hedral geometry. Each [MnCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001].
متن کامل1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocadmate(II)
In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001]. C-H⋯Cl inter-actions also occur.
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