Rotational alignment of products from NOCl1Sr chemiluminescent reaction
نویسندگان
چکیده
The chemiluminescent reactions Sr1NOCl→SrCl(A ,B)1NO are studied under the single collision conditions in a beam-gas arrangement. The product rotational alignment ^P2( Ĵ8–k̂)&520.40 60.05 for SrCl(B) is obtained from Sr1NOCl chemiluminescent reactions. In addition, the electronic state branching ratio and the product vibrational state distribution have been roughly estimated by simulating the chemiluminescent spectra of SrCl. Quasiclassical trajectory ~QCT! calculations for the Sr1NOCl reaction as a three-body system have been carried out. The calculated results agree well with the experimental ones. © 1998 American Institute of Physics. @S0021-9606~98!02029-7#
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Rotational Alignment of Products from the NOCl + Ca Chemiluminescent Reaction
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