New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands.
نویسندگان
چکیده
(μ-1,2-Peroxo)diiron(iii) complexes (-R) with dinucleating ligands (R-L) generated from the reaction of bis(μ-hydroxo)diiron(ii) complexes [Fe2(R-L)(OH)2](2+) (-R) with dioxygen in acetone at -20 °C provide a diiron-centred electrophilic oxidant, presumably diiron(iv)-oxo species, which is involved in aromatic ligand hydroxylation.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 45 2 شماره
صفحات -
تاریخ انتشار 2016