OPtIcal abSOrPtIOn SPectra Of MelanInS - a cOMParISOn Of theOretIcal and exPerIMental reSUlt

ثبت نشده
چکیده

The oligomeric hypothesis is supported by Atomic Force Microscopy (AFM) characterizations of synthetic eumelanins, formed by auto-oxidation or electrochemical oxidation of dihydroxyindole (DHI). Comparison of calculated absorption spectra to experimental spectra demonstrates a red shift in absorption with oxidation and stacking of the eumelanin, and validates the theoretical results. The work will lead to the development of better sun screenbased products, aiding the protection against, and the prevention of, skin cancer.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Optical Absorption Spectra of Melanins - a Comparison of Theoretical and Experimental Results

Researchers at Innovene, the University of San Antonio, and the University of California, Irvine, and Accelrys have used MS Modeling’s DMol, VAMP, and Discover codes to study the effect of aggregation and oxidation on the optical absorption of eumelanin oligomeric sheets. The oligomeric hypothesis is supported by Atomic Force Microscopy (AFM) characterizations of synthetic eumelanins, formed by...

متن کامل

Electronic Properties of Random Polymers: Modelling Optical Spectra of Melanins

Melanins are a group of complex pigments of biological origin, widely spread in all species from fungi to man. Among diverse types of melanins, the human melanins, eumelanins, are brown or black nitrogen-containing pigments, mostly known for their photoprotective properties in human skin. We have undertaken theoretical studies aimed to understand absorption spectra of eumelanins and their chemi...

متن کامل

Hydrothermal Synthesis, Characterization, Optical Properties of Lithium Meta- and Disilicate Nanomaterials and Theoretical Calculations

Highly crystalline and pure lithium metasilicate (Li2SiO3) and lithium disilicate (Li2Si2O5) nanomaterials were synthesized by hydrothermal method and characterized by PXRD technique. The changes in the morphology and particle size of the synthesized nanomaterials with reaction time were investigated using SEM technique. The UV-Vis and photoluminescence spectra of the compounds were studied. Th...

متن کامل

Hydrothermal Synthesis, Characterization, Optical Properties of Lithium Meta- and Disilicate Nanomaterials and Theoretical Calculations

Highly crystalline and pure lithium metasilicate (Li2SiO3) and lithium disilicate (Li2Si2O5) nanomaterials were synthesized by hydrothermal method and characterized by PXRD technique. The changes in the morphology and particle size of the synthesized nanomaterials with reaction time were investigated using SEM technique. The UV-Vis and photoluminescence spectra of the compounds were studied. Th...

متن کامل

Theoretical Investigation of Doping Concentration in Silicon Semiconductor Using Optical Principle

This paper investigates the amount of doping concentration in silicon semiconductor using optical principle.  Both donor and acceptor impurities of n type and p-type silicon semiconductor materials are computed at wavelength of 1550 nm. During the computation of donor and acceptor impurities, both reflection and absorption losses are considered. Theoretical result showed that transmitted intens...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2011