Tuning the reactivity of energetic nanoparticles by creation of a core-shell nanostructure.
نویسندگان
چکیده
This article presents a novel method for tuning the reactivity of nanoenergetic materials by coating a strong oxidizer nanoparticle (potassium permanganate; approximately 150 nm) with a layer of a relatively mild oxidizer (iron oxide). The measured reactivity for a nano-Al/composite oxidizer could be varied by more than a factor of 10, as measured by the pressurization rate in a closed vessel (psl/micros), by changing the coating thickness of the iron oxide. The composite oxidizer nanoparticles were synthesized by a new aerosol approach in which the nonwetting interaction between iron oxide and molten potassium permanganate aids the phase segregation of a nanocomposite droplet into a core-shell structure.
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ورودعنوان ژورنال:
- Nano letters
دوره 5 7 شماره
صفحات -
تاریخ انتشار 2005