The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles.

نویسندگان

  • Scott G Mitchell
  • Sumit Khanra
  • Haralampos N Miras
  • Thomas Boyd
  • De-Liang Long
  • Leroy Cronin
چکیده

Two topologically equivalent triangular POM aggregates based upon the Keggin () and Dawson () cluster species, with distinctive double {W-O-M} intra-molecular linkages involving Mn(III) and Co(III) ions are presented; both these compounds demonstrate electrocatalytic activity.

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عنوان ژورنال:
  • Chemical communications

دوره 19  شماره 

صفحات  -

تاریخ انتشار 2009