Interannual variability of air-sea O2 fluxes and the determination of CO2 sinks using atmospheric O2/N2

نویسندگان

  • Galen A. McKinley
  • Michael J. Follows
  • John Marshall
  • Song-Miao Fan
چکیده

[1] Motivated by the use of atmospheric O2/N2 to determine CO2 sinks under the assumption of negligible interannual variability in air-sea O2 fluxes, we examine interannual fluctuations of the global air-sea flux of O2 during the period 1980 – 1998 using a global ocean circulation and biogeochemistry model along with an atmospheric transport model. It is found that both the El Niño/Southern Oscillation (ENSO) cycle and wintertime convection in the North Atlantic are primary drivers of global air-sea oxygen flux interannual variability. Model estimated extremes of O2 flux variability are 70/+100 10 mol/yr (Tmol/yr), where positive fluxes are to the atmosphere. O2/N2 variability could cause an up to ±1.0 PgC/yr error in estimates of interannual variability in land and ocean CO2 sinks derived from atmospheric O2/N2 observations.

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تاریخ انتشار 2003