Beyond Dehydrocoupling: Group 2 Mediated Boron-Nitrogen Desilacoupling.
نویسندگان
چکیده
The alkaline-earth element bis(trimethylsilyl)amides, [Ae{N(SiMe3 )2 }2 (thf)2 ] [Ae=Mg, Ca, Sr], are effective precatalysts for boron-nitrogen bond formation through the desilacoupling of amines, RR'NH (R=alkyl, aryl; R'=H, alkyl, aryl), and pinBSiMe2 Ph. This reactivity also yields a stoichiometric quantity of Me2 PhSiH and provides the first example of a catalytic main-group element-element coupling that is not dependent on the concurrent elimination of H2 .
منابع مشابه
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 54 50 شماره
صفحات -
تاریخ انتشار 2015