Meso-meso linked core modified 22pi smaragdyrins with unusual absorption properties.

نویسندگان

  • Rajneesh Misra
  • Rajeev Kumar
  • Tavarekere K Chandrashekar
  • C H Suresh
چکیده

The synthesis of the first meso-meso linked core modified smaragdyrins with unusual single photon properties is reported.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and properties of Oxasmaragdyrins containing one Five-membered Heterocycle at Meso-position

The oxasmaragdyrins containing one five membered heterocycle such as pyrrole, thiophene and furan in place of one of the meso-phenyl group were synthesized by acid-catalyzed oxidative coupling reaction of meso-heterocycle substituted dipyrromethane with 16-oxatripyrrane in the presence of catalytic amount of trifluoroacetic acid followed by oxidation with DDQ. The smaragdyrin macrocycles contai...

متن کامل

Synthesis and spectroscopic properties of β-meso directly linked porphyrin–corrole hybrid compounds

The preparation of β-meso directly linked porphyrin-corrole hybrids was realized for the first time via an InCl3-catalyzed condensation reaction of 2-formyl-5,10,15,20-tetraphenylporphyrins with meso-substituted dipyrromethanes. Hybrid compounds have been characterized by 1H NMR, 13C NMR, 2D NMR, UV-vis absorption and fluorescence spectroscopy.

متن کامل

Surfactant Removal from Mesoporous ‎Silica Shell of Core-Shell Magnetic ‎Microspheres by Modified Supercritical ‎CO2‎

   In this paper, a kind of core–shell magnetic mesoporous microspheres of Fe3O4@SiO2@meso-SiO2 with high surface areawas prepared, where magnetic Fe3O4 nanospheres were used as the inner core, tetraethyl orthosilicate (TEOS) as silica source, and cetyltrimethylamonium bromide (CTAB) as pore forming agent. Methanol-enhanced s...

متن کامل

meso-Salicylaldehyde substituted BODIPY as a chemodosimetric sensor for cyanide anions.

The meso-salicylaldehyde substituted BODIPY was synthesized over a sequence of steps and characterized by X-ray crystallography, mass, NMR, absorption, fluorescence and electrochemical techniques. The crystal structure showed the presence of strong intramolecular hydrogen bonding between hydroxyl and formyl groups, which induces rigidity in the BODIPY core and makes the BODIPY relatively more f...

متن کامل

Carbazole substituted boron dipyrromethenes.

meso-Substituted BODIPY with N-butylcarbazole () was prepared and derivatized. Dibromo BODIPY , α-formyl BODIPY and β-formyl BODIPY were synthesized. All compounds were characterized by HRMS, NMR, UV-vis absorption, electrochemical and fluorescence techniques. The crystal structures of BODIPY and its dibromo derivative were also solved. In both the X-ray structures, the dihedral angle between t...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 44  شماره 

صفحات  -

تاریخ انتشار 2006