Fe b 19 97 Non magnetic molecular Jahn - Teller Mott insulators

نویسنده

  • Erio Tosatti
چکیده

Narrow-band conductors may turn insulating and magnetic as a consequence of strong electron-electron correlation. In molecular conductors, the concomitance of a strong Jahn-Teller coupling may give rise to the alternative possibility of a non-magnetic insulator, with or without a static cooperative Jahn-Teller distortion. In the latter case the insulator has Mott-like properties, with an interesting interplay between electron-electron repulsion and the Jahn-Teller effect, which is dynamical. We study this kind of non-magnetic insulator in a very simple E ⊗ e Jahn-Teller model and we discuss its general properties in a more general context, also in connection with the insulating state of K4C60 and Rb4C60. Typeset using REVTEX 1

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

THE ROLE OF JAHN-TELLER EFFECT ON THE MAGNETIC PROPERTIES OF Fe-BASED SEMIMAGNETIC SEMICONDUCTORS

We present energy spectrum calculations of 5E term of Fe++ ion taking into account crystal field, spin-orbit interaction, uniaxial stress, magnetic field and dynamic Jahn-Teller effect. Basing on the obtained energy spectra we calculate magnetic properties (specific heat and magnetization) of Fe-based Semimagnetic Semiconductors. We found that presence of the JahnTeller effect has very small in...

متن کامل

Abstract for an Invited Paper for the MAR07 Meeting of The American Physical Society Anti-Jahn-Teller effect and d-wave phonon mechanism in cuprates

for an Invited Paper for the MAR07 Meeting of The American Physical Society Anti-Jahn-Teller effect and d-wave phonon mechanism in cuprates HIROSHI KAMIMURA, Tokyo University of Science Undoped cuprates are Jahn-Teller (JT) Materials [1] and Mott AF insulators [2]. When holes are doped, the octahedrons or pyramids elongated by the JT effect shrink. We call such distortion against the JT effect ...

متن کامل

Mössbauer Effect Probe of Local Jahn-Teller distortion in Fe-doped Colossal Magnetoresistive Manganites

Local structure of the Fe-doped La1−xCaxMnO3 (x=0.00-1.00) compounds has been investigated by means of Mössbauer spectroscopy. 57Fe Mössbauer spectra provide a direct evidence of Jahn-Teller distortion in these manganites. On the basis of Mössbauer results, the Jahn-Teller coupling was estimated. It is noteworthy that Ca-concentration dependence of Jahn-Teller coupling strength is very consiste...

متن کامل

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA +U method

A generalization of the local density approximation (LDA) method for systems with strong Coulomb correlations is described which gives a correct description of the Mott insulators. The LDA + U method takes into account orbital dependence of the Coulomb and exchange interactions which is absent in the LDA. The scheme can be regarded as a ‘firstprinciples’ method because there are no adjustable p...

متن کامل

A Computational Study to Find the Vibrational Modes Connected with Specific Molecular Structures of Calculated Compound

The purpose of this research is to provide a deeper understanding of the planar high- symmetry configuration instability. In the ideal case, the distortion corresponds to the movements of nuclei along normal modes that belong to non-totally symmetric irreps of the high symmertry (HS) point group of molecule. The analysis of the structural distortion from the HS nuclear arrangements of the JT ac...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1997