[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate
نویسندگان
چکیده
In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis-(di-o-tolyl-phosphan-yl)methane (dtpm) ligand bridges one of the Ru-Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].
منابع مشابه
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis-(di-o-tolyl-phosphan-yl)methane ligand bridges one Ru-Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rin...
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The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(18)H(15)O(3)P)(CO)(9)], contains two crystallographically independent but similar mol-ecules. The bis-(diphenyl-arsino)methane ligand bridges an Ru-Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both the phosphite and arsine ligands are equatorial with respect to the Ru(3) trian...
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In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloro-methane solvent mol-ecule have a fractional site occupancy of 0.25; the dichloro-methane mol-ecule is disordered about an inversion centre. The bis-(di-o-tolyl-phosphan-yl)methane ligand bridges an Ru-Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded ...
متن کامل[μ-Bis(diphenylarsino)methane-1:2κ2 As:As′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate
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متن کامل[μ-Bis(diphenylarsino)methane-1:2κ2 As:As′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[(pentafluorophenyl)diphenylphosphine-3κP]-triangulo-triruthenium(0) chloroform monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(18)H(10)F(5)P)(CO)(9)]·CHCl(3), contains one mol-ecule of the triangulo-triruthenium complex and one mol-ecule of the disordered chloro-form solvent. The bis-(diphenyl-arsino)methane ligand bridges an Ru-Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphin...
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