A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state.
نویسندگان
چکیده
Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(III)(3)Mn(IV)O(4)] core into a centrosymmetric [Mn(III)(6)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 9 شماره
صفحات -
تاریخ انتشار 2012