Electrochemically active porous organic polymers based on corannulene.

Electrically and Electrochemically Active Composite Based on Polyester/Reduced Graphene Oxide/Polypyrrole with Remarkable Washing Durability

Porous polymer catalysts with hierarchical structures.

The emergence of porous organic polymers (POPs) has provided great opportunities for new applications in heterogeneous catalysis owing to their unprecedented intrinsic structural features such as high surface areas, extraordinary framework stabilities and chemically adjustable compositions. In this tutorial review, representative recent developments in the POPs-based catalysts with hierarchical...

Complete Double Epoxidation of Divinylbenzene Using Mn(porphyrin)-Based Porous Organic Polymers

A series of porphyrin-based porous organic polymers (PPOPs) were synthesized in excellent yields via the Yamamoto−Ullmann couplings of tetrabromo spirobifluorene with several brominated porphyrin monomers. After isolation and demetalation, the metal-free PPOP can be postsynthetically metalated to form a Mn−PPOP that is catalytically active toward the selective double-epoxidation of divinylbenze...

Electrochemically addressable trisradical rotaxanes organized within a metal-organic framework.

The organization of trisradical rotaxanes within the channels of a Zr6-based metal-organic framework (NU-1000) has been achieved postsynthetically by solvent-assisted ligand incorporation. Robust Zr(IV)-carboxylate bonds are forged between the Zr clusters of NU-1000 and carboxylic acid groups of rotaxane precursors (semirotaxanes) as part of this building block replacement strategy. Ultraviolet...

Redox-Active Metal-Organic Nanostructure Polymers and Their Remarkable Electrochemical Behavior

A number of redox-active coordination polymers (CPs) or metal- organic frameworks (MOFs) have been successfully synthesized using transition metals and bridging ligands. This article aims to deal with gathering the aforementioned disperse issues regarding the electroactive CPs. It also goes towards illustrating the effects of various factors on the electrochemical behavior of CPs including...