The significance of bromide in the Brust–Schiffrin synthesis of thiol protected gold nanoparticles† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc03266h
نویسندگان
چکیده
School of Chemistry, University of Manche [email protected] Division of Nuclear Engineering Science, Re Kumatori, Sennan, Osaka, 590-0494, Japan Diamond Light Source Ltd., Didcot, Oxford Synchrotron Soleil, L'Orme des Merisiers, S France Division of Sustainable Energy and Environ Engineering, Osaka University, Suita, Osaka Materials Sciences Research Center, Japan Tokai, Naka, Ibaraki, 319-1195, Japan Department of Materials Chemistry, Facu University, Otsu, Shiga 520-2194, Japan School of Chemical and Process Engineerin † Electronic supplementary informa 10.1039/c7sc03266h Cite this: Chem. Sci., 2017, 8, 7954
منابع مشابه
The significance of bromide in the Brust-Schiffrin synthesis of thiol protected gold nanoparticles.
The mechanism of the two-phase Brust-Schiffrin synthesis of alkane thiol protected metal nanoparticles is known to be highly sensitive to the precursor species and reactant conditions. In this work X-ray absorption spectroscopy is used in conjunction with liquid/liquid electrochemistry to highlight the significance of Br- in the reaction mechanism. The species [AuBr4]- is shown to be a preferab...
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