Chlorido(1,10-phenanthroline)[1,1,1-trifluoro-3-(2-thenoyl)acetonato]copper(II)
نویسندگان
چکیده
In the title compound, [Cu(C(8)H(4)F(3)O(2)S)Cl(C(12)H(8)N(2))], the Cu(II) ion exhibits a distorted square-pyramidal geometry. The coordination environment of the cation comprises two N atoms from 1,10-phenanthroline and two O atoms from thenoyltrifluoro-acetone in the basal plane and one Cl(-) anion at the apical site. There are weak inter-molecular C-H⋯Cl bonds.
منابع مشابه
catena-Poly[[chlorido(1,10-phenanthroline)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethylcyclobutyl]acetato}]
The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin-ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl-ate O atom from the pinononate anion, forming a CuN(2)ClO approximate square plane. A symmetry-generated pinononate O atom completes a square-based pyramidal geometr...
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The title complex, [Cu(C(3)H(2)N(3)O(2))Cl(C(12)H(8)N(2))], crystallizes with two independent mol-ecules in the asymmetric unit. Each Cu(II) atom is coordinated by an N atom and an O atom from the bidentate 1H-1,2,4-triazole-3-carboxyl-ate ligand, two N atoms from the 1,10-phenanthroline ligand, and the Cl atom. The coordination geometry is based on a ClN(3)O square pyramid. In the crystal stru...
متن کاملChlorido(2-methyl-4-oxo-4H-pyran-3-olato-κ 2 O 3,O 4)(1,10-phenanthroline-κ 2 N,N′)copper(II)
The copper(II) atoms in the two independent mol-ecules of the title compound, [Cu(C(6)H(5)O(3))Cl(C(12)H(8)N(2))], both adopt square-pyramidal geometries. The two coordinating atoms of the two heterocyclic ligands comprise the square plane, and the chlorine atom occupies the apical position of the coordination environment.
متن کاملCrystal structure of triaqua(1,10-phenanthroline-κ2 N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO 1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate
The title salt, [Co(C8H4F3O3)(C12H8N2)(H2O)3](C8H4F3O3), was obtained under solvothermal conditions by the reaction of 2,4,5-tri-fluoro-3-meth-oxy-benzoic acid with CoCl2 in the presence of 1,10-phenanthroline (phen). The Co(II) ion is octa-hedrally coordinated by two N atoms [Co-N = 2.165 (2) and 2.129 (2) Å] from the phen ligand, by one carboxyl-ate O atom [Co-O = 2.107 (1) Å] and by three O ...
متن کاملDi-μ-chlorido-bis[(1,10-phenanthroline-κ2 N,N′)(trichloroacetato-κO)copper(II)]
The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro-acetate ligand and two Cl(-) anions. In addition, there is a weak intra-molecular Cu⋯O inter-action o...
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