On the Reactions of CF3SF4C1, (CF3)2SF2, SF4, and 0SC12 with Trimethylsilyl Cyanide
نویسندگان
چکیده
A moderately stable hexacoordinated sulfur(VI) compound with four different kinds of ligands, CF3SF2(CN)2C1, results when CF3SF4CI is reacted with (CH3)3SiCN. The latter compound also gives F2S(CN)2 and (CF3)2S(CN)2 with SF4 and (CF3)2SF2, respectively. These tetracoordinated suifur(IV) compounds decompose rapidly at 25 °C but are stable at lower temperatures. With OSCl2 and SC12, the white solids OS(CN)2 and S(CN)2 result. This provides a new, convenient route to S(CN)2.
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