g-ray spectra from positron annihilation on atoms and molecules

Positron annihilation on a wide variety of atoms and molecules is studied. Room-temperature positrons confined in a Penning trap are allowed to interact with molecules in the form of low-pressure gases so that the interaction is restricted to binary encounters between a positron and a molecule. Data are presented for the g-ray spectra resulting from positrons annihilating in such interactions. The Doppler broadening of these spectra is a measure of the momentum distribution of the annihilating electron-positron pairs. Consequently, these spectra provide information about the electron and positron wave functions. Systematic studies of annihilation line shapes are discussed for noble gases, a variety of inorganic molecules, alkanes, alkenes, aromatics, and perfluorinated and partially fluorinated hydrocarbons. In the case of molecules, the measurements are used to determine the probability of positrons annihilating at specific locations in the molecule. For example, in the case of partially fluorinated hydrocarbons, we have been able to determine the relative probability of annihilation on the fluorine atoms and on the C-H bonds. Insights that these studies provide in understanding the interaction of low-energy positrons with atoms and molecules are discussed. @S1050-2947~97!05405-X#