Poly[(μ3-pyridine-4-carboxylato-κ3 O:O′:N)(pyridin-1-ium-4-carboxylato-κO)(thiocyanato-κN)cobalt(II)]
نویسندگان
چکیده
In the title compound, [Co(C6H5NO2)(NCS)(C6H4NO2)] n , the Co(2+) cation is coordinated by one N and two O atoms of three bridging pyridine-4-carboxyl-ate anions, one O atom of one zwitterionic pyridinium-4-carboxyl-ate ligand and one terminal N-bonding thio-cyanate anion within a distorted N2O3 trigonal bipyramid. The bridging coordination mode of the ligands leads to the formation of layers parallel to (-101). N-H⋯O hydrogen-bonding inter-actions within the layers and S⋯S contacts of 3.257 (3) Å between the layers lead to the cohesion of the structure.
منابع مشابه
cis-Triaqua[1,1′-(propane-1,3-diyl)bis(pyridin-1-ium-4-carboxylato)-κO]bis(thiocyanato-κN)manganese(II) dihydrate
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