Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T.
نویسندگان
چکیده
The complex [Tpm(*,Br)Cu(NCMe)]BF4 (Tpm(*,Br) = HC(3,5-Me2-4-Br-pyrazolyl)3) catalyses the aziridination of alkenes and the amidation of cyclic ethers with chloramine-T as the nitrene source and the ionic liquid [bmim]PF6 as the reaction medium (bmim = 1-n-butyl-3-methylimidazolium). High conversions have been obtained over several cycles of catalyst recovery and reuse.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 4 شماره
صفحات -
تاریخ انتشار 2009