Thermodynamic consistency of energy and virial routes: an exact proof within the linearized Debye-Hückel theory.

نویسندگان

  • Andrés Santos
  • Riccardo Fantoni
  • Achille Giacometti
چکیده

The linearized Debye-Hückel theory for liquid state is shown to provide thermodynamically consistent virial and energy routes for any potential and for any dimensionality. The importance of this result for bounded potentials is discussed.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 131 18  شماره 

صفحات  -

تاریخ انتشار 2009