Synthesis and Features of Luminescent Bromo- and Iodohectorite Nanoclay Materials
نویسندگان
چکیده
The smectites represent a versatile class of clay minerals with broad usage in industrial applications, e.g., cosmetics, drug delivery, bioimaging, etc. Synthetic hectorite Na0.7(Mg5.5Li0.3)[Si8O20](OH)4 is a distinct material from this class due to its low-cost production method that allows to design its structure to match better the applications. In the current work, we have synthesized for the first time ever nanoclay materials based on the hectorite structure but with the hydroxyl groups (OH−) replaced by Br− or I−, yielding bromohectorite (Br-Hec) and iodohectorite (I-Hec). It was aimed that these materials would be used as phosphors. Thus, OH− replacement was done to avoid luminescence quenching by multiphonon de-excitation. The crystal structure is similar to nanocrystalline fluorohectorite, having the d001 spacing of 14.30 Å and 3 nm crystallite size along the 00l direction. The synthetic materials studied here show strong potential to act as host lattices for optically active species, possessing mesoporous structure with high specific surface area (385 and 363 m2 g−1 for Br-Hec and I-Hec, respectively) and good thermal stability up to 800 ◦C. Both materials also present strong blue-green emission under UV radiation and short persistent luminescence (ca. 5 s). The luminescence features are attributed to Ti3+/TiIV impurities acting as the emitting center in these materials.
منابع مشابه
Synthesis and characterization of some novel linear azo-azomethine compounds based on 1-bromo, 4-4-4-nitrophenylazo phenoxy butane
The reaction of some carbocyclic and heterocyclic Schiff bases with the synthesized 1-bromo, 4-[4-(4-nitrophenylazo) phenoxy] butane and formation of novel linear azo-azomethine compounds in good to excellent yields were investigated. The compounds were fully characterized by UV-Vis, FT-IR, 1H NMR spectroscopic techniques and elemental analysis. Effects of various solvents on their visible abso...
متن کاملA Novel Initiator of [5-(benzyloxy)-4-oxo-4H-pyran-2-yl]methyl-2-bromo-2-methylpropanoateas in Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate
A novel nano-initiator containing kojic acid moiety, [5-(benzyloxy)-4-oxo-4H-pyran-2-yl)methyl-2-bromo-2-methylpropanoate was synthesized by the reaction of 5-(benzyloxy)-2-(hydroxymethyl)-4H-pyran-4-one with 2-bromoisobutyryl bromide in triethylamine and used as initiator in the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate in the presence of Cu(0)/CuCl2and N,N...
متن کاملFlexural Behavior of Fiber–Metal Laminates Reinforced with Surface-Functionalized Nanoclay
The effects of surface-functionalized Na+-montmorillonite nanoclay particles on the flexural behavior of E-glass fiber-reinforced aluminum (GLARE) laminates were investigated. The nanoclay particles were subjected to surface functionalization using 3-(trimethoxysilyl)propylamine to increase their compatibility with the epoxy matrix and improve their dispersion within the matrix. Expe...
متن کاملEffect of Nanoclay on Tensile Properties of Hybrid Polymer matrix Composites
---------------------------------------------------------------------***--------------------------------------------------------------------Abstract Composite materials are widely used because of their extreme properties. Researchers working on fabrication of new composite materials worldwide to enhance the applicability of these materials. There are very few works about the effect of nanoclay ...
متن کاملSynthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium (IV) Complexe : trans-[Pt(4-mpy)2Cl4]
The new trans-[Pt(4-mpy)2Cl4] (1) complex (4-mpy is 4-methylpyridine) was prepared from the reaction of H2PtCl6.6H2O with 4-methylpyridine in methanol. Synthesized complex was thoroughly characterized by elemental analysis, IR and 1H-NMR spectroscopy.Elemental analysis data (C, H, N) support the general composition of the title complex and the structure have been established by single-crystal X...
متن کامل