Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes.
نویسندگان
چکیده
We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature.
منابع مشابه
Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 59 شماره
صفحات -
تاریخ انتشار 2015