(1-Naphthyliminomethyl)ferrocene
نویسنده
چکیده
In the title mol-ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo-penta-dienyl rings are approximately eclipsed and the inter-planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclo-penta-dienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthal-ene ring system is 47.1 (1)°. The C-N=C-C torsion angle is 177.32 (5)°.
منابع مشابه
Bis[1-(2-naphthyliminomethyl)-2-naphtholato-κ2 N,O]copper(II)
In the title complex, [Cu(C(21)H(14)NO)(2)], the Cu(II) atom, lying on an inversion center, is coordinated by two bidentate 1-(2-naphthyl-imino-meth-yl)-2-naphtholate ligands in a trans arrangement, forming a slightly distorted square-planar coordination geometry. The mean planes of two naphthyl systems of the ligand make a dihedral angle of 40.32 (11)°.
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