Linking Seasonal Foliar Chemistry to VSWIR-TIR Spectroscopy across California Ecosystems
نویسنده
چکیده
The synergy between the reflected solar spectrum (Visible Near Infrared/ Short Wave Infrared or VSWIR) and the emitted spectrum (Thermal Infrared or TIR) for identifying plant species’ foliar chemistry has been largely unexplored. In the 2013 spring and summer seasons, fresh leaves from sixteen common shrub and tree species were sampled from locations ranging from the Sierra Nevada mountains, the Central Valley, and coastal Santa Barbara. Partial Least Squares (PLS) regression analysis with leave-one-out cross validation was used to relate spectral response at wavelengths from 0.3 μm to 15.4 μm to laboratory measured biochemical concentrations of nitrogen, lignin, and cellulose. For each biochemical component, three PLS regression models were fit using different portions of the spectrum: VSWIR spectrum (0.3 2.5 μm), TIR spectrum (2.5 – 15.4 μm), and the entire spectrum (0.3 – 15.4 μm). Using the TIR spectrum for prediction, the relationship between predicted biochemical values versus laboratory measurements was especially strong for all three biochemical constituents. The combination of VSWIR and TIR increased the R2 of regression models compared to VSWIR spectrum regression alone, signifying that the incorporation of TIR data would improve discrimination of these components. Although the incorporation of TIR wavelengths improved discrimination, high coefficients of the PLS regression suggests that the VSWIR wavelengths were the primary predictor used for identification of biochemical properties. Nevertheless, strong relationships with the thermal spectrum imply that wavelengths in the TIR spectrum will further improve the prediction of biochemical concentrations. Bio: Susan Meerdink is a MA/PhD student in the UCSB Geography Department. She holds degrees in both Ecology and Geographic Information Sciences from the University of Northern Iowa. During her undergraduate career, Susan was a recipient of a scholarship from the NASA Space Grant Consortium where she worked on various remote sensing applications such as identifying possible climatic factors that influence the geographic shift and spatial fidelity of Taimyr calving grounds. Her current research focuses on using remote sensing techniques to determine foliar chemistry and biophysical properties as they deviate seasonally and across California ecosystems.
منابع مشابه
Atmospheric Correction for Global Mapping Spectroscopy: ATREM Advances for the HyspIRI Preparatory Campaign
Orbital imaging spectrometers, such as the proposed Hyperspectral Infrared Imager (HyspIRI) mission, will provide global, multi-year Visible Shortwave Infrared (VSWIR) reflectance maps. Monitoring the Earth’s surface at high spectral resolution will advance our understanding of changing ecosystems and land use. These applications depend on reliable correction of atmospheric scattering and absor...
متن کاملControls over foliar N:P ratios in tropical rain forests.
Correlations between foliar nutrient concentrations and soil nutrient availability have been found in multiple ecosystems. These relationships have led to the use of foliar nutrients as an index of nutrient status and to the prediction of broadscale patterns in ecosystem processes. More recently, a growing interest in ecological stoichiometry has fueled multiple analyses of foliar nitrogen:phos...
متن کاملOrganismic-Scale Remote Sensing of Canopy Foliar Traits in Lowland Tropical Forests
Airborne high fidelity imaging spectroscopy (HiFIS) holds great promise for bridging the gap between field studies of functional diversity, which are spatially limited, and satellite detection of ecosystem properties, which lacks resolution to understand within landscape dynamics. We use Carnegie Airborne Observatory HiFIS data combined with field collected foliar trait data to develop quantita...
متن کاملInvestigation of the structure of water at hydrophobic and hydrophilic interfaces by angle-resolved TIR Raman spectroscopy.
To analyse the surface- or interface-specific molecular structure of a condensed molecular system, it is important to measure the spectra of molecules near the surface. Total internal reflection (TIR) Raman spectroscopy is a sensitive technique for surface or interfacial analysis because it retrieves spectra in the region within ca. 100 nm of a surface. However, since the width of the interface...
متن کاملCharacterization and quantification of the cross-linking of linear low density polyethylene with silane grafting by Fourier transform infrared (FTIR) spectroscopy
The way of making cross-linkable polyethylene through silane grafting has gained much attention in recentyears because of its various advantages such as easy processing, low cost and capital investment andfavorable properties in the processed materials. This work deals with silane grafting and moisture crosslinkingof linear low density polyethylene (LLDPE). The grafting reaction was performed i...
متن کامل