A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II)
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چکیده
The title complex, [PtCl(2)(C(18)H(40)P(2))], contains a Pt(II) center in an approximately square-planar geometry [cis angle range = 88.09 (3)-91.39 (3)°; twist angle = 1.19 (5)°]. The Pt-P bond lengths of 2.2536 (8) and 2.2513 (8) Å and the Pt-Cl bond lengths of 2.3750 (8) and 2.3588 (8) Å are normal. This crystal form is a polymorph of a structure reported previously [Harada, Kai, Yasuoka & Kasai (1976 ▶). Bull. Chem. Soc. Jpn, 49, 3472-3477].
منابع مشابه
Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ2 N:N′]bis(μ3-cyclobutane-1,1-dicarboxylato-κ3 O,O′:O′′:O′′′)dimanganese(II)]
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