Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity.

نویسندگان

  • Martin Lammert
  • Michael T Wharmby
  • Simon Smolders
  • Bart Bueken
  • Alexandra Lieb
  • Kirill A Lomachenko
  • Dirk De Vos
  • Norbert Stock
چکیده

A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.

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عنوان ژورنال:
  • Chemical communications

دوره 51 63  شماره 

صفحات  -

تاریخ انتشار 2015