Enhanced enantioselectivity of 3-methylcyclohexanone by mixed diol host compounds.
نویسندگان
چکیده
3-Methylcyclohexanone is only partially resolved by crystallisation with a chiral diol host compound (ee 40%), but when recrystallised from an equimolar mixture of the chiral diol host and a similar but achiral host we obtain complete resolution. The latter host acts as a nucleation inhibitor and the enhanced resolution is attributed to kinetic effects.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 68 شماره
صفحات -
تاریخ انتشار 2012