Biaxial nematic order induced by smectic fluctuations.
نویسندگان
چکیده
We report on a series of measurements on the microscopic structure and the magneto-optical properties of a calamitic liquid crystalline compound in its nematic phase. Structural studies show the existence of short-range, tilted smectic order consistent with pretransitional effects above an underlying smectic phase. Concomitantly, magneto-optical results exhibit the existence of an optic axis not collinear with the uniaxial director. This apparent biaxial nature is discussed within the context of coupling between the tensor nematic and the smectic order parameters.
منابع مشابه
Surface alignment, anchoring transitions, optical properties, and topological defects in the nematic phase of thermotropic bent-core liquid crystal A131.
We study optical, structural, and surface anchoring properties of thermotropic nematic bent-core material A131. The focus is on the features associated with orientational order as the material has been reported to exhibit not only the usual uniaxial nematic but also the biaxial nematic phase. We demonstrate that A131 experiences a surface anchoring transition from a perpendicular to tilted alig...
متن کاملDynamics of the nematic phase of a bent-core liquid crystal.
The dielectric fluctuations in the uniaxial nematic phase of a bent-core liquid crystal have been studied by dynamic light scattering. Polarization selection of the scattering cross-section reveals one mode due to ordinary director fluctuations and, in the lower part of the nematic phase, a second mode attributable to fluctuations of the biaxial order parameter. The director fluctuations are ap...
متن کاملPhase behaviour of hard board-like particles.
We examine the phase behaviour of colloidal suspensions of hard board-like particles (HBPs) as a function of their shape anisotropy, and observe a fascinating spectrum of nematic, smectic, and columnar liquid-crystalline phases, whose formation is entirely driven by excluded volume effects. We map out the phase diagram of short and long HBPs by gradually modifying their shape from prolate to ob...
متن کاملDensity Functional Theory of Model Systems with the Biaxial Nematic Phase
Present work is a theoretical study on the stability of the thermotropic biaxial nematic liquid crystal phase in model systems. Its main aim is to present the phase diagrams of spatially uniform liquid mesophases and to identify the molecular parameters that influence the stability of the biaxial nematic. The diagrams are obtained by means of the Local Density Functional Theory in low density a...
متن کاملNovel biaxial bilayered fluid mesophases
2014 In a substance with a substituted chlorine on the central ring of an alkylphenyl cyanobenzoyloxybenzoate we obtain evidence in a biaxial fluid medium for anomalies of periodicity similar to those initially found in the nematic and smectic A phases of the unsubstituted series (« DBn »). From X-ray studies, microscopic observations, D.S.C. recordings and magnetic measurements, a new mesomorp...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 86 2 Pt 1 شماره
صفحات -
تاریخ انتشار 2012