Synthesis of nitrogen-substituted methylenecyclopropanes by strain-driven Overman rearrangement of cyclopropenylmethyl trichloroacetimidates.
نویسندگان
چکیده
Nitrogen-substituted methylenecyclopropanes have been prepared by a strain-driven Overman rearrangement of cyclopropenylmethyl trichloroacetimidates. The reaction proceeds at room temperature and without the need of a transition-metal catalyst. Furthermore, it has been shown that C-3-substituted cyclopropenylmethyl trichloroacetimidates undergo a hydrolytic ring-opening reaction to form allenylcarbinols.
منابع مشابه
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 79 17 شماره
صفحات -
تاریخ انتشار 2014