Mechanical properties of a metal-organic framework containing hydrogen-bonded bifluoride linkers.
نویسندگان
چکیده
We report the mechanical properties of a framework structure, [Cu2F(HF)(HF2)(pyz)4][(SbF6)2]n (pyz = pyrazine), in which [Cu(pyz)2](2+) layers are pillared by HF2(-) anions containing the exceptionally strong F-H···F hydrogen bonds. Nanoindentation studies on single-crystals clearly demonstrate that such bonds are extremely robust and mechanically comparable with coordination bonds in this system.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 40 شماره
صفحات -
تاریخ انتشار 2013