Supramolecular assembly in a Janus-type urea system.
نویسندگان
چکیده
A pyrazolyl urea ligand adopts two possible conformations with the urea NH groups directed either outward or inward. Metal coordination enforces the outward conformation resulting in either anion complexation or self-association and hence extended supramolecular assemblies including a hexameric barrel that persists in solution.
منابع مشابه
A versatile strategy towards non-covalent functionalization of graphene by surface-confined supramolecular self-assembly of Janus tectons
Two-dimensional (2D), supramolecular self-assembly at surfaces is now well-mastered with several existing examples. However, one remaining challenge to enable future applications in nanoscience is to provide potential functionalities to the physisorbed adlayer. This work reviews a recently developed strategy that addresses this key issue by taking advantage of a new concept, Janus tecton materi...
متن کاملCorrection: Substituent interference on supramolecular assembly in urea gelators: synthesis, structure prediction and NMR.
Correction for 'Substituent interference on supramolecular assembly in urea gelators: synthesis, structure prediction and NMR' by Francesca Piana et al., Soft Matter, 2016, 12, 4034-4043.
متن کاملArchitectural control of urea in supramolecular 1D strontium vanadium oxide chains.
A facile bottom-up approach for the controlled self-assembly of infinite strontium vanadium oxide chains is presented. Two novel one-dimensional strontium-linked polyoxovanadate chains have been isolated by linkage of decavanadate clusters with strontium(ii) ions. To control the architecture dimensions, urea was used as a critical control parameter which allowed tuning of the intra- and intermo...
متن کاملA review on the effects of urea in skin disorders
Alterations in barrier function are associated with a number of skin diseases, including xerosis, atopic dermatitis, and psoriasis. Urea, a component of the natural moisturizing factor of the skin, plays an important role in the preservation of skin hydration and integrity. Several studies have investigated the effects of urea in the clinical setting. Here, we summarize the available clinical e...
متن کاملSurface-confined self-assembled Janus tectons: a versatile platform towards the noncovalent functionalization of graphene.
A general strategy for simultaneously generating surface-based supramolecular architectures on flat sp(2) -hybridized carbon supports and independently exposing on demand off-plane functionality with controlled lateral order is highly desirable for the noncovalent functionalization of graphene. Here, we address this issue by providing a versatile molecular platform based on a library of new 3D ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 50 12 شماره
صفحات -
تاریخ انتشار 2014