Renewable resource-based poly(dodecyloate) by carbonylation polymerization.
نویسندگان
چکیده
Cobalt-catalyzed step growth polymerization of undec-10-en-1-ol and CO affords aliphatic polyesters (Mn > 10(4) g mol(-1)) based entirely on renewable resources.
منابع مشابه
Supplementary data: Renewable-resource based poly( dodecyloate) by carbonylation
Materials and General Considerations. Unless noted otherwise, all manipulations were carried out under an inert gas atmosphere using standard glovebox or Schlenk techniques. Pyridine was distilled from CaH2, and toluene from sodium under argon. Undec-IO-en-I-ol supplied by ACME Synthetic Chemicals (Mumbai, India) was degassed prior to use. Carbon monoxide (3.7 grade) supplied by Air Liquide was...
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ورودعنوان ژورنال:
- Chemical communications
دوره 36 شماره
صفحات -
تاریخ انتشار 2009