(2E)-1-(2,6-Dichloro-3-fluorophenyl)-3-phenylprop-2-en-1-one
نویسندگان
چکیده
In the title compound, C(15)H(9)Cl(2)FO, the F atom shows positional disorder over two positions, with site-occupancy factors of 0.747 (4) and 0.253 (4). The dihedral angle between the rings is 86.37 (10)°. In the crystal, C-H⋯O contacts connect the mol-ecules into chains along the c axis. The shortest inter-centroid distance between two aromatic systems is 3.6686 (12) Å and is apparent between the halogenated rings.
منابع مشابه
(2E)-1-(2,6-Dichloro-3-fluorophenyl)-3-(4-fluorophenyl)prop-2-en-1-one
In the title compound, C(15)H(8)Cl(2)F(2)O, the C=C double bond is in the E configuration. In the cyrstal, C-H⋯O hydrogen bonds connect the mol-ecules into chains along the c axis. A π-π inter-action of 3.628 (1) Å is also observed between two polyhalogenated benzene rings. The dichloro-substituted ring exhibits partial disorder over two sets of sites, with site-occupancy factors of 0.573 (3) a...
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In the title compound, C22H15Cl2FO2, a chalcone derivative featuring a threefold-halogenated aromatic substituent, the conformation about the C=C bond is E. In the crystal C-H⋯F and C-H⋯Cl contacts connect the mol-ecules into undulating sheets parallel to (101). In addition, C-H⋯π inter-actions are also present.
متن کامل4-[(1E)-3-(2,6-Dichloro-3-fluorophenyl)-3-oxoprop-1-en-1-yl]benzonitrile
In the title mol-ecule, C(16)H(8)Cl(2)FNO, the benzene rings form a dihedral angle of 78.69 (8)°. The F atom is disordered over two positions in a 0.530 (3):0.470 (3) ratio. The crystal packing exhibits π-π inter-actions between dichloro-substituted rings [centroid-centroid distance = 3.6671 (10) Å] and weak inter-molecular C-H⋯F contacts.
متن کامل(2E)-1-(2,6-Dichloro-3-fluorophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
There are two independent mol-ecules in the asymmetric unit of the title compound, C(16)H(11)Cl(2)FO(2). The F atom equally populates both meta positions of the 6-dichloro-3-fluoro-phenyl ring in each mol-ecule, resulting in 0.5 occupancy for both the F and H atoms in these positions. The dihedral angle between the mean planes of the benzene rings are 77.5 (2) and 89.8 (8)°in the two mol-ecules...
متن کامل1-(4-Fluorophenyl)-3-hydroxy-3-phenylprop-2-en-1-one
In the crystal structure the title compound, C(15)H(11)FO(2), the molecule exists in the enol form. It is stabilized by an intra-molecular O-H⋯O hydrogen bond, in which the donor O-H and acceptor H⋯O distances are almost equal. The dihedral angle between the two benzene rings is 22.30 (4)°.
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