2-(1-Adamantyl)-1,3-diphenylpropan-2-ol
نویسندگان
چکیده
In the title compound, C(25)H(30)O, the adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.15 (9)-111.55 (9)°. The dihedral angle between the benzene rings is 46.91 (4)° and the conformation is stabilized by a weak intra-molecular C-H⋯π inter-action.
منابع مشابه
(S)-2-(1-Methylindolin-2-yl)-1,3-diphenylpropan-2-ol
The five-membered ring in the the title mol-ecule, C(24)H(25)NO, fused with the phenyl-ene ring, is almost planar (r.m.s. deviation = 0.023 Å), with the methyl-ene C atom deviating most from this mean plane [0.031 (1) Å]. The tertiary N atom shows a flattened pyramidal configuration [Σ(angles at N) = 350.3 (6)°].
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The title compound, C(15)H(11)BrO(2), exists as a diketone in which the two benzoyl groups are nearly perpendicular to each other [dihedral angles = 79.9 (1) and 87.4 (1)° in the two independent mol-ecules].
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In the title mol-ecule, C(23)H(20)N(4)O(2)S, the triazole ring forms dihedral angles of 150.3 (2), 77.3 (2) and 77.6 (2)°, respectively, with the furan ring and the phenyl rings. The furan ring is almost perpendicular to the central phenyl ring, making a dihedral angle of 86.0 (3)°.
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The title compound, [PdCl(2)(C(23)H(23)NO)]·CH(3)OH, was obtained by the reaction of 1-(2,6-dimethyl-phenyl-imino)-1,2-diphenyl-propan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hy-droxy-limine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex mol-...
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In the title mol-ecule, C(25)H(21)ClN(4)OS, the triazole ring forms dihedral angles of 47.9 (2), 84.5 (2) and 3.9 (2)° with the two phenyl rings and the chloro-phenyl ring, respectively. The chloro-phenyl ring, the triazole ring and the conjugative linker between the two aromatic rings are nearly coplanar with an r.m.s. deviation of 0.0483 (2) Å and a maximum deviation of 0.0911 (2) Å.
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