Unique reactivity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane.
نویسندگان
چکیده
We demonstrate an unprecedented H2 generation activity in the hydrolytic dehydrogenation of ammonia borane over acid oxidation- and subsequent high temperature-treated CNT immobilized Pt nanocatalysts to combine the merits of defect-rich and oxygen group-deficient surfaces and unique textural properties of supports as well as optimum particle size of Pt.
منابع مشابه
The dehydrogenation of ammonia-borane catalysed by dicarbonylruthenacyclic(II) complexes.
The reactivity of ruthenacyclic compounds towards ammonia-borane's dehydrogenation was investigated by considering both hydrolytic and anhydrous conditions. The study shows that the highly soluble μ-chlorido dicarbonylruthenium(II) dimeric complex derived from 4-tert-butyl,2-(p-tolyl)pyridine promotes, with an activation energy E(a) of 22.8 kcal mol(-1), the complete hydrolytic dehydrogenation ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 17 شماره
صفحات -
تاریخ انتشار 2014