[(4-Methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine-κ3 N,N′,N′′]bis­(thio­cyanato-κS)copper(II) dichloro­methane hemisolvate

نویسندگان

  • Yan Qi
  • Yang Li
  • Zheng-Ping Ma
  • Qiu-Yun Chen
چکیده

The title compound, [Cu(NCS)(2)(C(20)H(21)N(3))]·0.5CH(2)Cl(2), crystallized with two independent complex mol-ecules (A and B) in the asymmetric unit, accompanied by one dichloro-methane solvent mol-ecule. Each Cu(II) atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine ligand and two from the thio-cyanate ligands. In the crystal, the B mol-ecules are linked via C-H⋯S inter-actions, forming chains propagating along [100].

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012