Oxygen isotopes in cellulose identify source water for archaeological maize in the American Southwest

Maize (Zea mays) was a primary food crop for aboriginal societies of the arid American Southwest. Water used for maize production in these arid zones could have come from precipitation and runoff during the summer monsoon, from perennial streams and springs, or from stored soil water fed by snowmelt. The oxygen stable isotope ratio (dO) of summer and winter precipitation on the Colorado Plateau naturally differ by more than 10& providing a powerful tool for distinguishing winterfrom summerderived water sources used in cultivation of maize. We investigated whether variation in dO of potential source waters is preserved in the dO of cellulose (dOcellulose) of maize cobs by growing four aboriginal and one modern maize variety in pots irrigated with water of known dO composition. The dOcellulose values of cobs ranged from 26.8 to 36.4& (averaged within varieties) and were highly correlated with dO values of the source irrigation water ( 15.8 to 8.2&). Cob dOcellulose from five archaeological sites on the Colorado Plateau in southeastern Utah ranged from 27.3 to 34.6&, closely matching the range of values observed in experimental plants. A dOcellulose model developed originally for tree rings was parameterized and applied to the archaeological maize cobs. The model indicated that monsoonal precipitation accounted for 0e20% of the moisture for archaeological cob samples from a site adjacent to a perennial stream and 43e98% for samples from an upland site, more distant from a perennial water source. These results reveal the potential for using dOcellulose to investigate prehistoric irrigation practices and source water used for maize production in the American Southwest. 2005 Elsevier Ltd. All rights reserved.